Well, there's a simpler solution, use XMPlay Shortcuts! XD (well, workaround, if you need intellitype)
For example, I want to bind the Play multimedia button to Play/Pause of XMPlay: go to Options, choose Shortcuts, select "Current Track - Play / Pause", click on the "Click here to enable the shortcut", click on Multimedia button on your keyboard, select the new shortcut (in my case I got a new shortcut to my 0xB3 button), select "make global", and that's it.